- 收听数
- 0
- 性别
- 保密
- 听众数
- 21
- 最后登录
- 2022-1-9
- QQ
- UID
- 2264
- 阅读权限
- 40
- 帖子
- 918
- 精华
- 0
- 在线时间
- 685 小时
- 注册时间
- 2012-12-24
- 科研币
- 63
- 速递币
- 394
- 娱乐币
- 2273
- 文献值
- 29
- 资源值
- 0
- 贡献值
- 0
|
速递书局
封面: |
|
题名: |
Lewis Basicity and Affinity Scales: Data and Measurement |
作者: |
Christian Laurence, Jean-Franois Gal |
出版社: |
Wiley |
出版日期: |
2010-02-01 |
ISBN: |
0470749571, 0470681896 |
附属页: |
齐全 |
书签: |
有 |
格式: |
清晰PDF |
内容简介: |
The Lewis concept of acids and bases is discussed in every general, organic and inorganic chemistry textbook. This is usually just a descriptive treatment, as it is not possible to devise a single numerical scale suitable for all occasions. However quantitative Lewis acid-base chemistry can be developed by compiling reaction-specific basicity scales which can be used in specific branches of chemistry and biochemistry.
Lewis Basicity and Affinity Scales: Data and Measurementbrings together for the first time a comprehensive range of Lewis basicity/affinity data in one volume. More than 2400 equilibrium constants of acid-base reactions, 1500 complexation enthalpies, and nearly 2000 infrared and ultraviolet shifts upon complexation are gathered together in 25 thermodynamic and spectroscopic scales of basicity and/or affinity. For each scale, the definition, the method of measurement, an exhaustive database, and a critical discussion are given. All the data have been critically examined; some have been re-measured; literature gaps have been filled by original measurements; and each scale has been made homogeneous.
This collection of data will enable experimental chemists to better understand and predict the numerous chemical, physical and biological properties that depend upon Lewis basicity. Chemometricians will be able to apply their methods to the data matrices constructed from this book in order to identify the factors which influence basicity and basicity-dependent properties. In addition, measured experimental basicities and affinities are essential to computational chemists for the validation, calibration and establishment of reliable computational methods for quantifying and explaining intermolecular forces and the chemical bond.
Lewis Basicity and Affinity Scales: Data and Measurement is an essential single-source desktop reference for research scientists, engineers, and students in academia, research institutes and industry, in all areas of chemistry from fundamental to applied research. |
求助帖链接: |
- |
本帖子中包含更多资源
您需要 登录 才可以下载或查看,没有帐号?快速注册
-
总评分: 速递币 + 60
查看全部评分
|